Non-polymer PFAS can build up in blood protein of animals, and is not always removed quickly. This means that predators eating PFAS-contaminated food will have higher levels in their bloodstream, and concentrations can increase up the food chain. Studies suggest that build up of PFAS is similar to those of other Persistent Organic Pollutants such as DDT.PFAS are estimated to be settling in arctic regions at rates of tens to hundreds of kilograms per year (25-850kg per year), depending on the specific PFAS chemical in question. Certain PFAS are released as gases to the environment and are blown a long way by wind and air currents in the atmosphere,. These gas PFAS will over time degrade to more persistent chemicals like PFOS and PFOA. This may be one reason why PFAS of environmental concern have been found in remote regions such as the Arctic as well as near PFAS production sitesPFAS including PFOS and PFOA have been found in air samples around Europe. The chemicals are found in small quantities, but appear in almost all samples tested. PFAS enters the atmosphere both from factories and the air inside our homes. https://www.ncbi.nlm.nih.gov/pubmed/17554424 PFAS is found in treated waste water from industrial and domestic sources and has been found in both rivers and groundwater. Conventional drinking water processes will not remove PFAS.PFAS-coated clothes that are thrown away will often end up either incinerated or in landfill. Unless incinerated at very high temperatures (>1000oC), fluorinated polymers could release more harmful PFAS during burning. PFAS of environmental concern have also been found in landfill leachate. Non-polymer PFAS are used in the production of fluorinated polymers. The manufacture of stain-resistant finishes generally releases these PFASs into the environment, both by air and water emissions. They are very hard to remove during water treatment. Workers in textiles factories are some of the population most exposed to these potentially harmful chemicals. Small quantities of PFAS will be removed during wash and wear of products containing PFAS. This includes fluorinated polymers used on stain-resistant coatings, and non-polymers that remain on clothes after production (Lassen et al. 2015).Most UK waste still ends up in landfill, and this includes PFAS-containing products. Studies have shown that the liquid coming from landfills (known as leachate) often contain non-polymer PFAS chemicals. In the USA the total quantities were estimated at 563-638 kg in 2013. To properly break down PFAS chemicals high temperature (1000oC or more) incineration is recommended. Incineration of municipal waste does not necessarily reach these temperatures (min temp. required is 850oC), and the incomplete breakdown could release non-polymer PFAS.Wash and wear of clothing that contains PFAS-based stain-resistant or water repellent finishes release PFAS to the environment. Coatings are thought to lose effectiveness after 20-30 washes. This can include non-polymer PFAS, remnant from production or as a break-down product of side-chain polymers (Lassen et al. 2015). The manufacture of stain-resistant finishes releases PFAS into the environment, both by air and water emissions. PFAS are very hard to remove during water treatment. Industrial emissions are estimated to be the biggest source of these chemicals to the environment.

New study shows PFAS can’t be cleaned up and must be prevented

A new study published today shows that even with massive financial investments in PFAS clean up across Europe, less than 2% of these “forever chemicals” would be removed from the environment. This study adds to the growing body of evidence and consensus amongst scientists that the only way to protect human health and the environment from PFAS is to prioritise source control.  

The study gives the first comprehensive overview of how much PFAS can be removed from the environment based on investing heavily in soil, landfill, wastewater and drinking water remediation. It highlights that without turning off the tap on PFAS emissions, efforts to tackle the widespread contamination will become an endless and costly cycle, leaving human health and ecosystems exposed.

Credit - Robert Bye, UnSplash
Credit - Robert Bye, UnSplash

Costly clean up with limited results strengthens the need for source control 

Estimates of PFAS clean up costs have varied massively between studies. Previously, the Forever Pollution Project estimated clean-up costs for legacy PFAS in Europe, assuming emissions had stopped, to be in the region of 1-6 billion euros. However, this isn’t our current reality. To address the ongoing increasing emissions of PFAS, experts believe it could lead to costs of 52-200 billion euros per year.  

However, this new study shows that even with such a substantial investment in the most aggressive remediation measures, less than 2% of current PFAS emissions would be addressed. This analysis was based on a hypothetical scenario involving large-scale remediation using emerging technologies and this figure does not include trifluoroacetic acid (TFA) precursors or fluoropolymers.  

Lead Author of the study Alison L. Ling says: “We are making so much PFAS, and they are so persistent and mobile that remediation alone cannot keep pace with ongoing emissions,”. She adds: “Clean-ups make sense where they meaningfully reduce exposures and health risks, but even unprecedented spending on remediation could not significantly reduce the amount of PFAS already in the environment.” 

TFA and other short chained PFAS are making remediation efforts even more difficult 

The study emphasises the increasing significance of ultra-short chain PFAS, such as TFA, which are both challenging to remove and increasingly prevalent in our environment. The rising prevalence of TFA underscores a more extreme form of environmental buildup, intensifying both the complexity and cost of remediation efforts. 

“The implication that less than 2% of current PFAS emissions can be remediated may seem surprising at first,” adds Hans Peter Arp, a leading expert in PFAS and TFA, “but when you see the increasing amounts of PFAS, particularly TFA, accumulating in forests, groundwater, grasslands, food-supply systems, ecosystems, and even in our own blood, it makes sense. We cannot remove PFAS from trees, lakes and our cereals. The world is becoming increasingly polluted with diffuse PFAS pollution that will forever change the chemistry of the planet and can never be remediated.” 

Fidra and the University of York’s research released last year, shows that the UK is already highly contaminated with TFA – with 98% of the 54 river sites tested found to be contaminated. One site reported the second-highest level of TFA contamination ever recorded globally at a concentration of 78,464 ng/L. 

 ”The high concentrations of TFA measured recently in UK rivers is only the tip of the iceberg regarding how much TFA is in the UK environment. There is likely far more TFA in the land, including farmland, where it can be much more costly and impractical to remediate TFA. The only way to protect the future food and water supply in the UK is to prioritise source control to prevent further release and accumulation of TFA into the environment“ Hans Peter Arp adds. 

Source control is the only way forward  

Current approaches that focus on cleaning up localised contamination are inadequate for persistent, mobile chemicals like PFAS. The authors of this study are calling for a shift in environmental management approaches to PFAS, to prioritise prevention.  

This year, the UK released it’s PFAS plan outlining how the government will tackle forever chemical pollution. Though the plan is a step in the right direction and includes some promising actions on understanding sources of PFAS, managing risks linked to their use, and supporting shifts to safer alternatives, the plan falls short on controlling PFAS pollution at its source. The UK’s Environmental Audit Committee (EAC) reached a similar conclusion, stating that the plan is insufficient and recommended a rapid restriction on non-essential uses of PFAS following its inquiry. 

Fidra and others are calling for the UK Government to phase out PFAS from all non-essential uses. This could be achieved through alignment with EU chemical regulation, including the EU’s proposed universal PFAS restriction. Turning off the tap remains the most critical and immediate action required to tackle PFAS pollution and protect public and environmental health for future generations.